Speed Racer (technically, I didn't actually realize it was anime until later)
Doraemon and Gunbuster VHS sub tapes my cousins had and gave to me. I watched everything I could find on TV after that, Pokemon, Cardcaptors (I didn't realize how much it sucked ass), Outlaw Star, anything Gundam, Sailor Moon, etc. I had already seen a lot of stuff by the time it was on TV over here though due to my cousins and their "connections" with various fansubbers. They also got me into digital fansubbing, etc.